Polar and nonpolar substances interact best among themselves

"Like attracts like" is an old saying, and nowhere is it more true than in polar and nonpolar molecules, which tend to interact with their own kind. Just as water molecules interact with one another through polarity-induced hydrogen bonds, any molecule that is itself polar will interact with other polar molecules by weak (5+ to 5-) attractions in hydrogen bonds. If a polar molecule interacts with water in this way, it is called hydrophilic ("water-loving").

What about nonpolar molecules? For example, carbon (electronegativity 2.5) forms nonpolar bonds with hydrogen (electronegativity 2.1). The resulting hydrocarbon mole-cule—that is, a molecule containing only hydrogen and carbon atoms—is nonpolar, and in water it tends to aggregate with other nonpolar molecules rather than with polar water. Such molecules are known as hydrophobic ("water-hating"), and the interactions between them are called hydrophobic interactions. It is important to realize that hy-drophobic substances do not really "hate" water; they can form weak interactions with it (recall that the electronegativities of carbon and hydrogen are not exactly the same). But these interactions are far weaker than the hydrogen bonds between the water molecules, and so the nonpolar substances keep to themselves.

2.14 Water Molecules Surround Ions When an ionic solid dissolves in water, polar water molecules cluster around cations or anions, blocking their reassociation into a solid and forming a solution.

These weak interactions between nonpolar substances are enhanced by van der Waals forces, which result when two atoms of nonpolar molecules are in close proximity. These brief interactions are a result of random variations in the electron distribution in one molecule, which create an opposite charge distribution in the adjacent molecule. Although a single van der Waals interaction is brief and weak at any given site, the summation of many such interactions over the entire span of a large nonpolar molecule can produce substantial attraction. van der Waals forces are important in maintaining the structures of many biologically important substances.

Chemical Reactions: Atoms Change Partners

A chemical reaction occurs when atoms combine or change their bonding partners. Consider the combustion reaction that takes place in the flame of a propane stove. When propane (C3H8) reacts with oxygen gas (O2), the carbon atoms become bonded to oxygen atoms instead of to hydrogen atoms, and the hydrogen atoms become bonded to oxygen instead of carbon (Figure 2.15). As the covalently bonded atoms change partners, the composition of the matter changes, and propane and oxygen gas become carbon dioxide and water. This chemical reaction can be represented by the equation

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Responses

  • Fre-weini
    How nonpolar substances interact?
    8 years ago
  • asmeret
    How do polar and nonpolar molecules interact?
    8 years ago
  • salvia sandyman
    How do nonpolar substances interact with water?
    5 years ago

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