Yy

SEnz

H3C~S(5

Oj 1

CO2H OH orsellinic acid

aldol reaction, aromatization

C-alkylation || O FPP

O-methylation SAM

ho2c

demethylmycophenolic acid

C-alkylation || O FPP

O-methylation SAM

farnesyl PP t co2h

5-methylorsellinic acid oxidation of methyl to CH2OH, then lactonization

CO2H OH orsellinic acid farnesyl PP t

5-methylorsellinic acid

coh o phthalide intermediate

H3CO.

ho2c ho2c

H3CO.

ho2c

mycophenolic acid

demethylmycophenolic acid mycophenolic acid

Figure 3.36

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