R = H, permethrin R = CN, cypermethrin
electrophilic addition giving tertiary cation
loss of proton via cyclopropyl ring formation
hydrolysis of phosphate ester; oxidation of alcohol to acid
P-oxidation etc fl
P-oxidation etc fl jasmonic acid
jasmolone pathway operates in the formation of jasmonic acid (Figure 5.20), which forms part of a general signalling system in plants, particularly the synthesis of secondary metabolites in response to wounding or microbial infection.
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